Edexcel A-Level Chemistry sample questions and answers (9CH0)

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57 sample questions and answers

Taken from every topic of Edexcel A-Level Chemistry, specification 9CH0. The full guide has 1,534.

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Paper 1, Paper 3

Atomic Structure and the Periodic Table

68 questions in the guide, across 5 subtopics. More from this topic

  1. Protons, neutrons, electrons and isotopes

    What is meant by the mass number of an atom?

    Show the answer
    The total number of protons and neutrons in the nucleus of an atom
  2. Protons, neutrons, electrons and isotopes

    How is the number of electrons in a negative ion calculated?

    Show the answer
    Number of electrons = number of protons plus the magnitude of the charge
  3. Relative atomic mass and the mass spectrum

    Why does the mass spectrum of a diatomic element show multiple peaks?

    Show the answer
    Because peaks correspond to all possible combinations of isotopes in the molecule

Paper 1, Paper 2, Paper 3

Bonding and Structure

69 questions in the guide, across 4 subtopics. More from this topic

  1. Ionic bonding

    How are cations formed?

    Show the answer
    By an atom losing one or more electrons.
  2. Ionic bonding

    What is an isoelectronic series?

    Show the answer
    A set of ions (or atoms) that all have the same number of electrons and the same electron configuration.
  3. Covalent bonding, dative bonding and the shapes of molecules

    Which is stronger and shorter, a C-C single bond or a C=C double bond?

    Show the answer
    The C=C double bond is shorter and stronger.

Paper 1, Paper 2, Paper 3

Redox I

35 questions in the guide, across 2 subtopics. More from this topic

  1. Oxidation numbers

    What is the oxidation number of fluorine in its compounds?

    Show the answer
    Always -1.
  2. Oxidation numbers

    In Cr₂O₇²⁻, what oxidation number does chromium take?

    Show the answer
    +6 (seven oxygens at -2 give -14; ion charge -2, so the two Cr total +12, i.e. +6 each).
  3. Oxidation, reduction, disproportionation and half-equations

    In general, how do metals form ions, and what happens to their oxidation number?

    Show the answer
    They lose electrons to form positive ions, so their oxidation number increases.

Paper 1, Paper 3

Inorganic Chemistry and the Periodic Table

168 questions in the guide, across 11 subtopics. More from this topic

  1. Flame tests and how they work

    What flame colour is produced by lithium compounds?

    Show the answer
    Crimson/red
  2. Thermal decomposition of nitrates and carbonates

    What gaseous products are released when calcium nitrate decomposes on heating?

    Show the answer
    Nitrogen dioxide and oxygen
  3. Carrying out flame tests and testing the gases

    Where in the Bunsen flame should the wire be held during a flame test?

    Show the answer
    At the edge of a non-luminous Bunsen flame

Paper 1, Paper 2, Paper 3

Formulae, Equations and Amounts of Substance

134 questions in the guide, across 8 subtopics. More from this topic

  1. The mole, molar mass and empirical formula

    State the formula used to calculate the amount of substance in moles from mass.

    Show the answer
    n = m/M, where n is the amount in moles, m is the mass in grams, and M is the molar mass in g mol⁻¹.
  2. The ideal gas equation and molar volume

    Calculate the amount of substance when pressure = 158000 Pa, volume = 0.0016 m³, gas constant = 8.31 J K⁻¹ mol⁻¹, temperature = 344 K.

    Show the answer
    Amount of substance = (158000 × 0.0016) ÷ (8.31 × 344) = 0.0884 mol.
  3. Equations, concentration and reacting quantities

    Convert a volume of 724 cm³ into dm³.

    Show the answer
    Volume = 724 ÷ 1000 = 0.724 dm³.

Paper 2, Paper 3

Organic Chemistry I

202 questions in the guide, across 14 subtopics. More from this topic

  1. Formulae, homologous series and functional groups

    What is a general formula?

    Show the answer
    An algebraic formula that can represent any member of a homologous series.
  2. IUPAC nomenclature

    State the IUPAC prefix for a ten-carbon chain.

    Show the answer
    Dec-
  3. Stereoisomerism and E/Z nomenclature

    In E/Z nomenclature, what does the Z isomer indicate about the positions of higher priority groups?

    Show the answer
    The higher priority groups are on the same side of the double bond (zusammen means together).

Paper 2, Paper 3

Modern Analytical Techniques I

45 questions in the guide, across 3 subtopics. More from this topic

  1. Mass spectrometry

    In a mass spectrum, a loss of 15 mass units from the molecular ion indicates the loss of which group?

    Show the answer
    CH₃ (a methyl group).
  2. Mass spectrometry

    What does the term m/z represent in mass spectrometry?

    Show the answer
    The mass-to-charge ratio of an ion.
  3. Infrared spectroscopy and the characteristic absorptions

    What type of peak does C=C stretching in alkenes produce in an IR spectrum?

    Show the answer
    A characteristic absorption peak at a specific wavenumber range.

Paper 1, Paper 3

Energetics I

39 questions in the guide, across 2 subtopics. More from this topic

  1. Enthalpy changes, standard definitions and calorimetry

    Define the standard enthalpy change of reaction.

    Show the answer
    The enthalpy change when the molar amounts shown in the equation react under standard conditions, with all substances in their standard states.
  2. Enthalpy changes, standard definitions and calorimetry

    What value of the specific heat capacity of water is normally used?

    Show the answer
    4.18 J per gram per kelvin.
  3. Hess's law and bond enthalpies

    Define bond enthalpy.

    Show the answer
    The energy required to break one mole of a specified covalent bond with all species in the gaseous state.

Paper 2, Paper 3

Kinetics I

32 questions in the guide, across 3 subtopics. More from this topic

  1. Collision theory and factors affecting rate

    What does activation energy mean?

    Show the answer
    The minimum energy that colliding particles must have for a reaction to take place.
  2. Collision theory and factors affecting rate

    Why does increasing the surface area of a solid reactant increase the rate?

    Show the answer
    More reactant particles are exposed at the surface, so collisions with them are more frequent.
  3. Maxwell-Boltzmann distribution and temperature

    What does the total area under a Maxwell-Boltzmann curve represent?

    Show the answer
    The total number of particles.

Paper 1, Paper 3

Equilibrium I

24 questions in the guide, across 2 subtopics. More from this topic

  1. Dynamic equilibrium and Le Chatelier's principle

    What type of system is required for a reaction to reach equilibrium?

    Show the answer
    A closed system, where no reactants or products can enter or leave.
  2. Dynamic equilibrium and Le Chatelier's principle

    In which direction does an increase in total pressure shift a gaseous equilibrium?

    Show the answer
    Towards the side with fewer moles of gas.
  3. The equilibrium constant Kc

    What concentrations are used in the Kc expression?

    Show the answer
    The concentrations of the species at equilibrium.

Paper 1, Paper 3

Equilibrium II

23 questions in the guide, across 2 subtopics. More from this topic

  1. Partial pressures and Kp

    What do the mole fractions of all the gases in a mixture add up to?

    Show the answer
    1.
  2. Partial pressures and Kp

    Which species are included in a Kp expression?

    Show the answer
    Only gases; pure solids and pure liquids are omitted.
  3. Calculating Kp and the effect of conditions

    How is the total number of moles of gas used when calculating partial pressures?

    Show the answer
    It is used to find each mole fraction before multiplying by the total pressure.

Paper 1, Paper 3

Acid-Base Equilibria

73 questions in the guide, across 5 subtopics. More from this topic

  1. Bronsted-Lowry acids and bases, and the pH scale

    What forms when an acid donates a proton?

    Show the answer
    The acid forms its conjugate base.
  2. Bronsted-Lowry acids and bases, and the pH scale

    Once hydrogen ion concentration is known, how is pH calculated?

    Show the answer
    pH = −log₁₀[H⁺]
  3. Strong and weak acids, Ka and Kw

    What assumption is made about the equilibrium concentration of a weak acid HA when the degree of dissociation is small?

    Show the answer
    The equilibrium concentration of HA approximately equals the initial concentration of the acid.

Paper 1, Paper 3

Energetics II

70 questions in the guide, across 4 subtopics. More from this topic

  1. Lattice energy

    When calculating the enthalpy change of solution, why must you consider more than one enthalpy of hydration value?

    Show the answer
    Separate enthalpy of hydration values exist for cations and anions, and both must be considered when calculating the overall enthalpy change of solution.
  2. Lattice energy

    Why is the enthalpy of hydration of Al³⁺ more exothermic than that of Na⁺?

    Show the answer
    Al³⁺ has a higher charge and smaller radius, giving it a much higher charge density, which results in stronger ion-dipole interactions with water.
  3. Born-Haber cycles and electron affinity

    State the Hess's law relationship used to find lattice energy from a Born-Haber cycle.

    Show the answer
    The enthalpy of formation equals the sum of the atomisation enthalpies, the ionisation energies and the electron affinities, plus the lattice energy. Rearranging gives the lattice energy.

Paper 1, Paper 3

Redox II

62 questions in the guide, across 4 subtopics. More from this topic

  1. Standard electrode potentials and the hydrogen electrode

    What is meant by the standard electrode potential of a half-cell?

    Show the answer
    The voltage of that half-cell measured relative to the standard hydrogen electrode under standard conditions.
  2. Standard electrode potentials and the hydrogen electrode

    Why is platinum used in the standard hydrogen electrode?

    Show the answer
    It is inert and provides a surface for the reaction and a means of electrical contact.
  3. Electrochemical cells, emf and cell diagrams

    At which electrode does reduction occur?

    Show the answer
    At the positive electrode.

Paper 1, Paper 3

Transition Metals

123 questions in the guide, across 9 subtopics. More from this topic

  1. Electron configuration and what makes a transition metal

    State the electronic configuration of copper.

    Show the answer
    [Ar] 3d¹⁰ 4s¹
  2. Complex ions, ligands and the colour of transition metal ions

    State a characteristic property of transition metal ions in solution.

    Show the answer
    They form coloured ions in solution.
  3. Coordination number, monodentate ligands and the shapes of complexes

    Explain why ammonia acts as a monodentate ligand.

    Show the answer
    Ammonia has a lone pair on the nitrogen atom that can form one dative bond to a metal ion.

Paper 2, Paper 3

Kinetics II

74 questions in the guide, across 4 subtopics. More from this topic

  1. Rate equations, orders and the rate constant

    What is the rate constant, k?

    Show the answer
    The proportionality constant in the rate equation linking rate to the reactant concentrations.
  2. Rate equations, orders and the rate constant

    What are the units of the rate constant for a first-order reaction overall?

    Show the answer
    s⁻¹.
  3. Determining orders from experiments

    What is the shape of a rate-concentration graph for a first-order reaction?

    Show the answer
    A straight line through the origin.

Paper 2, Paper 3

Organic Chemistry II

113 questions in the guide, across 8 subtopics. More from this topic

  1. Chirality

    In an Sₙ1 reaction of a chiral halogenoalkane, what happens in the first step?

    Show the answer
    The chiral halogenoalkane loses the halide ion to form a carbocation
  2. Aldehydes, ketones and their oxidation

    Why is the carbonyl carbon open to attack by a nucleophile?

    Show the answer
    Oxygen is considerably more electronegative than carbon, so the C=O bond is strongly polarised and the carbon carries a partial positive charge that attracts an electron-rich species.
  3. Reduction and nucleophilic addition of HCN

    How is the reducing agent written in equations for these reactions?

    Show the answer
    As [H], so the reduction of propanone is written CH₃COCH₃ + 2[H] → CH₃CH(OH)CH₃.

Paper 2, Paper 3

Organic Chemistry III

129 questions in the guide, across 10 subtopics. More from this topic

  1. The structure of benzene and the evidence for it

    What enthalpy of hydrogenation would be predicted for cyclohexatriene based on the Kekulé structure?

    Show the answer
    Approximately three times the enthalpy of hydrogenation of cyclohexene.
  2. Electrophilic substitution of benzene

    What reagents are required for the nitration of benzene?

    Show the answer
    A mixture of concentrated nitric acid and concentrated sulfuric acid.
  3. Nitration, halogenation, Friedel-Crafts and phenol

    In Friedel-Crafts alkylation, how is the carbocation electrophile generated?

    Show the answer
    Aluminium chloride accepts a lone pair from the halogen of the halogenoalkane, generating a carbocation.

Paper 2, Paper 3

Modern Analytical Techniques II

51 questions in the guide, across 4 subtopics. More from this topic

  1. Carbon-13 and proton NMR

    How can you determine the number of distinct carbon environments in a molecule from its carbon-13 NMR spectrum?

    Show the answer
    The number of peaks in the spectrum equals the number of distinct carbon environments in the molecule.
  2. Carbon-13 and proton NMR

    Why do protons attached to different functional groups appear at different chemical shift values in proton NMR?

    Show the answer
    Because different chemical shift values correspond to protons in different chemical environments.
  3. Splitting, integration and the reference standard

    How many equivalent neighbouring protons on adjacent carbons produce a triplet in proton NMR?

    Show the answer
    Two equivalent neighbouring protons on adjacent carbons.

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